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Rust vs plants

this year i finally got a rain barrel set up, but its a bit old, its now entirely full though! only problem is that theres a noticable rust-hue to the water. will this hurt my plants if i water them with this water?
 
How did you catch it? Roof water? or some other way. I was always afraid of some roofs contaminating rain barrels through tar, old shingles, etc that might be up there.
 
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